Abstract
Regular pentagonal adhesive tiles were obtained by designing a cyclic fluoropentamer with an internal CF⋯HN H-bonded network and "sticky" edges that can glue the molecules together through intermolecular CArH⋯O=C H bonds. In the crystal they form the mathematically predicted densest all-pentagon 2D lattice with a packing density of 0.921 (see picture). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Ren, C., Zhou, F., Qin, B., Ye, R., Shen, S., Su, H., & Zeng, H. (2011). Crystallographic realization of the mathematically predicted densest all-pentagon packing lattice by C5-symmetric “sticky” fluoropentamers. Angewandte Chemie - International Edition, 50(45), 10612–10615. https://doi.org/10.1002/anie.201101553
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