Water radiolysis: Influence of oxide surfaces on H2 production under ionizing radiation

Abstract

The radiolysis of water due to ionizing radiation results in the production of electrons, H atoms, OH radicals, H3O+ ions and molecules (dihydrogen H2 and hydrogen peroxide H2O2). A brief history of the development of the understanding of water radiolysis is presented, with a focus on the H2 production. This H2 production is strongly modified at oxide surfaces. Different parameters accounting for this behavior are presented.