Abstract
"Chemical Equation Presented" Black AgSO4, synthesized for the first time by a displacement reaction, differs considerably from anhydrous sulfates of its Group 11 congeners: it has a very small electronic band gap (ca. 0.2 eV) and an anomalously strong one-dimensional antiferromagnetic ordering (J≈10 meV per Ag), which persists up to the onset of its thermal decomposition at about 120°C. Ag gray, O red, S yellow. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA.
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Malinowski, P. J., Derzsi, M., Mazej, Z., Jagličić, Z., Gaweł, B., ŁAsocha, W., & Grochala, W. (2010). AgIIso4: A genuine sulfate of divalent silver with anomalously strong one-dimensional antiferromagnetic Interactions. Angewandte Chemie - International Edition, 49(9), 1683–1686. https://doi.org/10.1002/anie.200906863
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