Phenomena occurring upon the sintering of a mixture of yttria–zirconia nanometric powder and sub-micrometric pure zirconia powder

Abstract

Mixtures of powders essentially differing in their particle morphology and size were applied to prepare polycrystals in a Y2 O3-ZrO2 system. An yttria–zirconia solid solution nanometric powder with a Y2 O3 concentration of 3.5% was prepared by subjecting co-precipitated gels to hydrothermal treatment at 240◦ C. The crystallization occurred in distilled water. The pure zirconia powders composed of elongated and sub-micrometer size particles were also manufactured through the hydrothermal treatment of pure zirconia gel, although in this case, the process took place in the NaOH solution. Mixtures of the two kinds of powder were prepared so as to produce a mean composition corresponding to an yttria concentration of 3 mol%. Compacts of this powder mixture were sintered, and changes in phase composition vs. temperature were studied using X-ray diffraction. The dilatometry measurements revealed the behavior of the powder compact during sintering. The polished surfaces revealed the microstructure of the resulting polycrystal. Additionally, the electron back scattering diffraction technique (EBSD) allowed us to identify symmetry between the observed grains. Hardness, fracture toughness, and mechanical strength measurements were also performed.