Hollow spheres to nanocups: Tuning the morphology and magnetic properties of single-crystalline α-Fe2O3 nanostructures

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Abstract

A bottom-up approach has been used to tune the morphology of single-crystalline hematite from hollow spheres to nanocups. The mechanism involves the formation of nanocups through buckling of the spheres, similar to a deflated ball (see picture). As the shape changes, there is a drastic change in magnetic properties. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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Jagadeesan, D., Mansoori, U., Mandal, P., Sundaresan, A., & Eswaramoorthy, M. (2008). Hollow spheres to nanocups: Tuning the morphology and magnetic properties of single-crystalline α-Fe2O3 nanostructures. Angewandte Chemie - International Edition, 47(40), 7685–7688. https://doi.org/10.1002/anie.200802626

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