An X-ray photoelectron spectros copy study of uranyl - Chitosan interaction

Abstract

An X-ray photoelectron spectroscopy study of uranium sorption by spherically-granulated chitosan in sulphate solutions, as well as the study of the nature of the U(VI) - chitosan interaction was carried out in this work. The X-ray photoelectron spectros -copy analysis showed that the uranyl - chitosan interaction results in the formation of complexes with aminogroup nitrogen, and possibly chitin ring oxygens and free hydroxyl groups in the equatorial plane. Under the UHV in the spectrometer chamber, the uranylamin and uranyl-hyroxide bonds were shown to break and tetravalent uranium compounds were shown to form on the sample surface. Hydroxyl groups were shown to evaporate. The calculated ΔG0 = -1,3 kJ/mol can be an evidence of several concurrent processes, some of which require energy, as well as of the formation of a surface chemical compound.