Self-assembly of [Au(CN)2]¯ complexes with tomato (Solanum lycopersicum) steroidal alkaloid glycosides to form sheet or tubular structures

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Abstract

Composites were prepared using [Au(CN)2]¯ complexes and steroidal alkaloid glycosides (SAGs) from tomato, including hydrophilic sugar and hydrophobic aglycone groups. Supra-molecular sheet, tubular and unique structures were obtained, depending on the molecular structure of the SAG. Polymeric [Au(CN)2]1n units in these supramolecular structures resulted in aurophilic interactions that produced luminescent aggregates, depending on the SAG.

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Toohara, S., Tanaka, Y., Sakurai, S., Ikeda, T., Tanaka, K., Gon, M., … Kuroiwa, K. (2018). Self-assembly of [Au(CN)2]¯ complexes with tomato (Solanum lycopersicum) steroidal alkaloid glycosides to form sheet or tubular structures. Chemistry Letters, 47(8), 1010–1013. https://doi.org/10.1246/cl.180320

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