Synthesis, characterization and conductivity measurements of polyaniline and poly aniline/fly-ash composites

Abstract

Polyaniline (PANI) and polyaniline/fly ash (PANI/FA) composites with various concentrations of fly ash (20%, 40% and 50%) were synthesized by the process of in-situ polymerization. The samples were characterized by powder X-ray diffraction, thermogravimetric analysis, infrared spectroscopy, and scanning electron microscopy. Moreover, the dc conductivity of the samples was measured as a function of temperature in the range 80-290 K and it was found that the addition of FA decreases the conductivity. The temperature dependence of the dc conductivity for PANI and FA/PANI composites has been explained on the basis of the quasi one-dimensional variable hopping model. A very good agreement was found between the experimental data and the theory. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.