Abstract
The structure of a new ZIF-8 polymorph with quartz topology (qtz) is reported. This qtz-[Zn(mIm)2] phase was obtained by mechanically amorphising crystalline ZIF-8, before heating the resultant amorphous phase to between 282 and 316 °C. The high-temperature phase structure was obtained from powder X-ray diffraction, and its thermal behaviour, CO2 gas sorption properties and dye adsorption ability were investigated.
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CITATION STYLE
Thorne, M. F., Castillo-Blas, C., McHugh, L. N., Bumstead, A. M., Robertson, G., Sapnik, A. F., … Bennett, T. D. (2022). Formation of new crystalline qtz-[Zn(mIm)2] polymorph from amorphous ZIF-8. Chemical Communications, 58(85), 11949–11952. https://doi.org/10.1039/d2cc04241j
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