Abstract
The electronic structures of six substituted ferrocenes containing bromo, carbonyl, and phosphanyl substituents have been studied by UV photoelectron spectroscopy (UPS) and ΔSCF/TDDFT calculations. Our UPS data show that splitting of Fe3d ionizations strongly decreases vs. ferrocene upon introducing benzoyl, chlorophosphine or dialkylphosphanyl groups. © 2012 Elsevier B.V. All rights reserved.
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Kovač, B., Novak, I., Abdel-Rahman, O. S., & Winter, R. F. (2013). Photoelectron spectroscopy of some substituted ferrocenes. Journal of Organometallic Chemistry, 727, 64–67. https://doi.org/10.1016/j.jorganchem.2012.11.037
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