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Bioinspired iron-based catalyst for atom transfer radical polymerization

Angewandte Chemie - International Edition (2013) 52(46) 12148-12151
DOI: 10.1002/anie.201306337
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Abstract

Naturally occurring hemin, an iron-containing porphyrin, and its synthetic derivatives were used as atom transfer radical polymerization (ATRP; see picture) catalysts. The effects of the halide salt concentration, attachment of poly(ethylene glycol) moieties, and hydrogenation of the hemin vinyl groups on the catalyst performance were studied. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Simakova, A., Mackenzie, M., Averick, S. E., Park, S., & Matyjaszewski, K. (2013). Bioinspired iron-based catalyst for atom transfer radical polymerization. Angewandte Chemie - International Edition, 52(46), 12148–12151. https://doi.org/10.1002/anie.201306337

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