Hot-pressed wet-laid polyethylene terephthalate nonwoven as support for separation membranes

Abstract

In thiswork, a polyethylene terephthalate (PET) nonwoven supportwas prepared bywet-laid and hot-press technology and used as support for separation membranes. The properties of the PET nonwoven support were studied to determine the effect of hot-pressing parameters and PET fiber ratio, and were optimized by response surfacemethodology. Result showed that the PET nonwoven support with 62% low melting point PET (LPET-180) fibers obtained satisfactory properties and structure after hot pressing at 220 °C under the pressure of 9MPa for 20 s. The response surface analysis indicated that the temperature and time of hot pressing and the fiber ratio were the most important factors affecting the strength and air permeability of the PET nonwoven support. After hot pressing, the PET nonwoven support exhibited interconnected structure, small pore size, low porosity, and high strength. Then phase inversion technique was applied to prepare a polysulfone (PSF) layer on the PET nonwoven support and an ultra-thin polyamide (PA) active layer was prepared by interfacial polymerization on the PSF layer. The practicality of PET nonwoven support was verified by testing the pure water flux and retention of the PA composite membrane and the structural change of the PA composite membrane before and after use. The results proved the feasibility and remarkable application prospects of hot-pressed wet-laid PET nonwoven support as support for separation membranes.