Complex open-framework germanate built by 8-coordinated Ge 10 clusters

Abstract

A novel open-framework germanate |(C 5H 14N 2) 2(C 5H 12N 2) 0.5(H 2O) 2.5|[Ge 12.5O 26(OH) 2] with three-dimensional 10- and 11-ring channels, denoted as SU-67, has been synthesized under hydrothermal conditions using 2-methylpiperazine (MPP) as the structure-directing agent (SDA). The synthesis is intimately related to that of JLG-5, a tubular germanate built from Ge 7 clusters. The influences of synthesis parameters are discussed. A strong influence of the hydrofluoric acid quantity on the resulting cluster building units can be concluded. The framework of SU-67 is based on an elaborate topological pattern of connected Ge 10 clusters forming intersecting 10- and 11-ring channels and has a low framework density (12.4 Ge atoms per 1000 ̊ 3). We have discovered that the topology of SU-67 is a new 8-connected nce-8-I4 1/acd net. Strong hydrogen bonding among the organic SDAs, water molecules, and Ge 10 clusters resulted in helical networks in SU-67. © 2012 American Chemical Society.