Spatial confinement: A green pathway to promote the oxidation processes for organic pollutants removal from water

Abstract

Organic pollutants removal from water is pressing owing to the great demand for clean water. Oxidation processes (OPs) are the commonly used method. However, the efficiency of most OPs is limited owing to the poor mass transfer process. Spatial confinement is a burgeoning way to solve this limitation by use of nanoreactor. Spatial confinement in OPs would (i) alter the transport characteristics of protons and charges; (ii) bring about molecular orientation and rearrangement; (iii) cause the dynamic redistribution of active sites in catalyst and reduce the entropic barrier that is high in unconfined space. So far, spatial confinement has been utilized for various OPs, such as Fenton, persulfate, and photocatalytic oxidation. A comprehensive summary and discussion on the fundamental mechanisms of spatial confinement mediated OPs is needed. Herein, the application, performance and mechanisms of spatial confinement mediated OPs are overviewed firstly. Subsequently, the features of spatial confinement and their effects on OPs are discussed in detail. Furthermore, environmental influences (including environmental pH, organic matter and inorganic ions) are studied with analyzing their intrinsic connection with the features of spatial confinement in OPs. Lastly, challenges and future development direction of spatial confinement mediated OPs are proposed.