Organometallic Molecular Trees as Multielectron and Multiproton Reservoirs: CpFe+‐Induced Nonaallylation of Mesitylene and Phase‐Transfer Catalyzed Synthesis of a Redox‐Active Nonairon Complex

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Abstract

A reservoir of 9 electrons and 27 protons, complex 1 has 8±1 quasi‐equivalent redox centers. It is prepared from [CpFe(η6‐mesitylene)]+ by nonaallylation of the three methyl substituents, demetalation, conversion into the corresponding nonaol, and phasetransfer‐catalyzed reaction with [CpFe(FC6H4Me)]. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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Moulines, F., Djakovitch, L., Gloaguen, B., Thiel, W., Fillaut, J. ‐L, Delville, M. ‐H, … Boese, R. (1993). Organometallic Molecular Trees as Multielectron and Multiproton Reservoirs: CpFe+‐Induced Nonaallylation of Mesitylene and Phase‐Transfer Catalyzed Synthesis of a Redox‐Active Nonairon Complex. Angewandte Chemie International Edition in English, 32(7), 1075–1077. https://doi.org/10.1002/anie.199310751

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