Journal Article

Gold-catalyzed formal cycloaddition of 2-ethynylbenzyl ethers with organic oxides and α-diazoesters

Angewandte Chemie - International Edition (2013) 52(29) 7559-7563
DOI: 10.1002/anie.201303016
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Abstract

A world of possibilities: Gold-catalyzed reactions of 2-ethynylbenzyl ethers with organic oxides and α-diazoesters gave 1,3-dihydroisobenzofuran and naphthalene derivatives, respectively (see scheme; EWG=electron-withdrawing group). Mechanisms for the formation of the formal cycloadducts were elucidated by isotope labeling. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Pawar, S. K., Wang, C. D., Bhunia, S., Jadhav, A. M., & Liu, R. S. (2013). Gold-catalyzed formal cycloaddition of 2-ethynylbenzyl ethers with organic oxides and α-diazoesters. Angewandte Chemie - International Edition, 52(29), 7559–7563. https://doi.org/10.1002/anie.201303016

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