Antiferromagnetism and crystal-field effects in CeCuX3 (X=Al,Ga) compounds

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Abstract

We have studied two new tetragonal compounds, CeCuAl3 and CeCuGa3, which both display very large specific-heat, c(T), values at low temperature. CeCuAl3 orders antiferromagnetically below T N=3.0 K, while CeCuGa3 remains paramagnetic down to 0.4 K. The large values of c(T) in these and other cerium intermetallics are interpreted as resulting from an unusually small crystal-field splitting and the possible presence of atomic disorder.

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Mentink, S. A. M., Bos, N. M., Van Rossum, B. J., Nieuwenhuys, G. J., Mydosh, J. A., & Buschow, K. H. J. (1993). Antiferromagnetism and crystal-field effects in CeCuX3 (X=Al,Ga) compounds. Journal of Applied Physics, 73(10), 6625–6627. https://doi.org/10.1063/1.352534

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