Unravelling the CO2 capture and conversion mechanism of a NiRu-Na2O switchable dual-function material in various CO2 utilisation reactions

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Abstract

Time-resolved operando DRIFTS-MS was performed to elucidate the CO2 capture and conversion mechanisms of a NiRuNa/CeAl DFM in CO2 methanation, reverse water-gas shift, and dry reforming of methane. CO2 was captured mainly in the form of carbonyls and bidentate carbonates, and a spillover mechanism occurred to obtain the desired products.

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Merkouri, L. P., Martín-Espejo, J. L., Bobadilla, L. F., Odriozola, J. A., Penkova, A., Ramirez Reina, T., & Duyar, M. S. (2023). Unravelling the CO2 capture and conversion mechanism of a NiRu-Na2O switchable dual-function material in various CO2 utilisation reactions. Journal of Materials Chemistry A, 11(25), 13209–13216. https://doi.org/10.1039/d3ta01892j

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