Crystal structure of bis(2-{[(3-bromo-propyl)imino]methyl}phenolato-κ2N,O)- Copper(II)

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Abstract

In the title compound, [Cu(C10H11BrNO)2], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the CuII cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu - O and Cu - N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C - H⋯π interactions exist between the molecules.

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Ourari, A., Zoubeidi, C., Bouacida, S., Derafa, W., Merazig, H., & Weil, M. (2015). Crystal structure of bis(2-{[(3-bromo-propyl)imino]methyl}phenolato-κ2N,O)- Copper(II). Acta Crystallographica Section E: Structure Reports Online, 71(2), m33–m34. https://doi.org/10.1107/S2056989015001309

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