Investigation of the Geopolymerization Potential of aWaste Silica-Rich Diabase Mud

Abstract

Diabase mud (DM) is a silica-rich residue yielding from aggregate crushing and washing operations in quarries. This work focuses on identifying the geopolymerization potential of a diabase mud through characterization of its mineralogical composition, investigation of its reactivity, and assessment of the early compressive strengths of alkali activated mixtures formulated based on the mud’s dissolution results. The findings suggest that considerably low amounts of Al and Si metals were dissolved following the dissolution tests conducted on DM, however, the incorporation of small quantities of CEM I, gypsum, and metakaolin (MK) moderately at a Na2SiO3:NaOH ratio of 50:50 and with a molarity of NaOH of 4 M enhanced the geopolymerization compared to low L/S ratio mixtures cured at different conditions. When M was increasing, the high L/S ratio mixtures exhibited fluctuations in strengths, especially beyond a 10 M NaOH molarity. Maximum strengths of mixtures at equivalent molarity of 10 were achieved when the Na2SiO3:NaOH ratio reached 30:70, regardless of the ambient conditions and the presence of CEM I. The curing conditions, the ratio of Na2SO3:NaOH, and the presence of CEM I in the DM-based mixtures did not appear to significantly affect the mixture when NaOH concentration was between 2 M and 4 M; at higher molarities, however, these enhanced the strengths of the geopolymerized DM.