CP/MAS NMR of Heavy Spin-1/2 Nuclei at B0 = 2.35 T

Abstract

Perspectives of CP/MAS NMR at low external magnetic field (B0= 2.35 T) are discussed. Applications are illustrated for the case of heavy spin-1/2 nuclei such as 195Pt and 199Hg: 195Pt and 199Hg CP/MAS spectra of a variety of organometallic compounds are reported. Aspects of shielding anisotropies of 195Pt-35/37Cl interactions and of 31P-M (M = Cd, Hg, Pt) coupling in transition metal phosphine complexes will be briefly addressed. © Verlag der Zeitschrift für Naturforschung