Stereocontrolled synthesis of all of the possible stereoisomers of 3,11-dimethylnonacosan-2-one and 29-hydroxy-3,11-dimethylnonacosan-2-one. The female sex pheromone of the german cockroach

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Abstract

All of the possible stereoisomers of 3, 11 - dimethylnonacosan - 2 - one 1 and 29 - hydroxy - 3, 11 -dimethylnonacosan - 2 - one 2 were synthesized from (R)-(+)- citronellic acid as the chiral source. The natural pheromones were shown to be (3S,11S)-1 and (3S, 11S)-2 by direct comparisons. © 1981.

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Mori, K., Masuda, S., & Suguro, T. (1981). Stereocontrolled synthesis of all of the possible stereoisomers of 3,11-dimethylnonacosan-2-one and 29-hydroxy-3,11-dimethylnonacosan-2-one. The female sex pheromone of the german cockroach. Tetrahedron, 37(7), 1329–1340. https://doi.org/10.1016/S0040-4020(01)92448-2

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