Transport process of carbon dioxide in seawater and synthetic seawater

Abstract

Carbon dioxide (CO2) ocean sequestration technologies, such as dissolution into seawater, are important to mitigate global warming. In this study, solution processes of CO2 gas in seawater and synthetic seawater were experimentally and theoretically studied under various pressures and temperatures to evaluate the transport process of CO2 in seawater. The solubilities of CO2 in seawater and synthetic seawater were measured by a change in pressure due to absorption at pressures up to 3 MPa and the temperatures ranged from 276 K to 333 K. It was obtained that the solubilities of CO2 increase with an increase in pressure, but decrease with an increase in temperature. The solubility of CO2 in synthetic seawater decreases with an increase in salt concentration. Empirical correlations for solubilities of CO2 in seawater at various temperatures and pressures were obtained based on the experimental data. In the theoretical analysis for the solution of single CO2 bubble in seawater, the single CO2 bubble was assumed to be stationary and surrounded by infinite liquid seawater. The rate of solution of bubble in liquid is affected strongly by various parameters, such as solubility, diffusion coefficient, bubble radius, and temperature.