Incorporation of multilayered double hydroxides/sepiolite augments proton conductivity performance in low sulfonated polyether sulfone octyl sulfonamide

Abstract

Low-sulfonation-level polyether sulfone octyl sulfonamide (LSPSO) was blended with a layered double hydroxides (LDHs, Mg2AlCl)/sepiolite nanostructure clay as a filler to create an electrolyte membrane for fuel cell applications. Comprehensive characterization of the composite membranes was conducted, encompassing Fourier-transform infrared spectroscopy, X-ray diffraction, mechanical stability assessment, thermal gravimetric analysis, ion exchange capability, swelling characteristics, water uptake performance, and electrochemical impedance spectroscopy analysis. In comparison to the pristine LSPSO membrane, the presence of LDHs/sepiolite nanoarchitecture material within LSPSO exhibited superior water retention and proton conductivity values, especially at elevated temperatures. The proton conductivity of the composite membranes reached approximately 250 mS/cm, while the unmodified LSPSO membrane only achieved 35 mS/cm at 100 °C. Moreover, LSPSO composite membranes demonstrated enhanced chemical and thermal stability along with higher proton conductivity when compared to pristine LSPSO membranes. These findings highlight the potential of developing tailored LSPSO composite membranes to advance the prospects of commercial applications in proton exchange membrane fuel cells.