Dichlorido(5,10,15,20-tetraphenylporphyrinato-κ4N) antimony(V) hexachloridoantimonate(V)

Abstract

The asymmetric unit of the title compound, [Sb(C44H 28-N4)N4][SbCl6], consists of one half of an antimony(V) tetraphenylporphyrin complex cation and one half of an hexachloridoantimonate(V) anion. In the complex cation, the SbV atom lies on an inversion center and is octahedrally coordinated by four N atoms from a macrocyclic tetraphenylporphyrinate ligand and two chloride ions. The complex cation has approximately a planar core with a maximum deviation of 0.018 (5) Åfrom the porphyrin mean plane. The average Sb-N distance is 2.062 (11) Å, while the Sb-Cl distance is 2.355 (1) Å. The SbV atom of the anion is also located on an inversion center. The [SbCl6]octahedron exhibits rhombic distortion characterized by the Sb-Cl bond lengths [2.311 (3), 2.374 (2) and 2.393 (4) Å]. In the crystal, the cations and anions are linked C-H⋯Cl hydrogen bonds, forming a layer parallel to (211).