New core@shell nanogel based 2-acrylamido-2-methyl-1-propane sulfonic acid for preconcentration of Pb(II) from various water samples

Abstract

Poly(vinyl alcohol) core coated with poly(2-acrylamido-2-methyl-1-propanesulfonic acid-co-N-isopropylacrylamide) shell to produce well-define PVA@P(AMPS-co-NIPAm) core shell nanogels with a core of 25 ± 0.5 nm and shell of 5 ± 0.5 nm. The synthetic approach was produced by a surfactant free emulsion polymerization (SFEP). The specific area was found to be 1685.8 m2/g. The nanogels were studied in a batch adsorption for removal of Pb(II) ions and characterized by SEM, TEM, TGA and BET measurements. The results showed that the adsorption equilibrium data fitted the Langmuir isotherm and the kinetic studies are well described by the pseudo-second-order kinetic model. The Pb(II) maximum adsorption was 510.2 (mg/g) for PVA@P(90AMPS-co-10NIPAm) (wt.: wt%). The PVA@P(AMPS-co-NIPAm) nanogels were applied for extracting of Pb(II) in real different environmental water samples successfully with high recoveries reaches 104.4%.