Porous organic polymers with anchored aldehydes: A new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties

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Abstract

A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties. © 2014 The Royal Society of Chemistry.

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Guillerm, V., Weselinski, L. J., Alkordi, M., Mohideen, M. I. H., Belmabkhout, Y., Cairns, A. J., & Eddaoudi, M. (2014). Porous organic polymers with anchored aldehydes: A new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties. Chemical Communications, 50(16), 1937–1940. https://doi.org/10.1039/c3cc48228f

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