CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides

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Abstract

A CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides/PPh3 has been explored. This reaction proceeded smoothly through an alkyl/aryl radical (generated from organometallics) under mild conditions and produced the desired sulfide products in excellent yields.

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Fu, Y., Su, Y., Xu, Q. S., Du, Z., Hu, Y., Wang, K. H., & Huang, D. (2017). CuI promoted sulfenylation of organozinc reagents with arylsulfonyl chlorides. RSC Advances, 7(10), 6018–6022. https://doi.org/10.1039/c6ra27201k

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