A biochar selection method for remediating heavy metal contaminated mine tailings

Abstract

Approximately 390,000 abandoned mines across the US pose considerable, pervasive risks to human and environmental health; world-wide the problem is even greater. Lime, organic materials, and other amendments have been used to decrease metal bioavailability (e.g., Cd, Cu, Mn, Ni, Zn) in contaminated mine wastes and to promote plant community establishment for tailings stabilization. Biochar properties (e.g., alkaline pH, metal sorbing capabilities, available nutrients, improved soil water retention) make it a potential amendment for remediating metal contaminated mine tailings. A three-step procedure was developed to identify biochars that were most effective at reducing heavy metal availability, retaining metals, and subsequently selecting biochars for use in a soil amendment laboratory trial to ultimately be utilized in heavy metal contaminated mine land settings: Step (1) a synthetic precipitation leaching procedure extract of mine tailings was produced, representing potentially available metals, and used to identify metal removal properties of 28 different biochars (e.g., made from various feedstocks and pyrolysis or gasification conditions); Step (2) evaluate how well biochars retained previously sorbed metals; and Step (3) laboratory evaluation of the most promising biochars that removed and did not releases metals, applied at 0, 1, 2.5, and 5% (by wt) to mine tailings for reducing metal bioavailability. The reported methodology and results from this study could be used to quickly identify specific biochars and application rates to reduce mine tailings metal availability and aid in future remediation of abandoned mine sites globally.