A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

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Abstract

Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Brünsted acid. © 2013 The Royal Society of Chemistry.

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Rubio-Marqués, P., Leyva-Pérez, A., & Corma, A. (2013). A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes. Chemical Communications, 49(74), 8160–8162. https://doi.org/10.1039/c3cc44064h

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