Thermal expansion properties of three isostructural co-crystals composed of isosteric components: Interplay between halogen and hydrogen bonds

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Abstract

Co-crystallization of a symmetrical azo bipyridine with isosteric resorcinols affords isostructural co-crystals that exhibit linear thermal expansion along each axis. The thermal expansions involve interplay between intra-layer halogen and hydrogen bonds.

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Hutchins, K. M., Kummer, K. A., Groeneman, R. H., Reinheimer, E. W., Sinnwell, M. A., Swenson, D. C., & MacGillivray, L. R. (2016). Thermal expansion properties of three isostructural co-crystals composed of isosteric components: Interplay between halogen and hydrogen bonds. CrystEngComm, 18(43), 8354–8357. https://doi.org/10.1039/c6ce01674j

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