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Solvent Assisted Oxy-Cope Rearrangement of Diastereomeric 1,5-Hexaden-3-ols. A New Industrial Process for Polyprenyl Ketones

  • Fujita Y
  • Amiya S
  • Onishi T
  • et al.
Bulletin of the Chemical Society of Japan (1979) 52(7) 1983-1988
DOI: 10.1246/bcsj.52.1983
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Abstract

Oxy-Cope rearrangement of diastereomeric l,5-hexadien-3-ols, new key intermediates for terpenoids pio-duction in industrial scale, were investigated in neat systems and solvent assisted systems. Various solvents affecting the selectivity of [3,3]-shift were classified by means of NMR studies on hydroxyl proton exchange time.

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Fujita, Y., Amiya, S., Onishi, T., & Nishida, T. (1979). Solvent Assisted Oxy-Cope Rearrangement of Diastereomeric 1,5-Hexaden-3-ols. A New Industrial Process for Polyprenyl Ketones. Bulletin of the Chemical Society of Japan, 52(7), 1983–1988. https://doi.org/10.1246/bcsj.52.1983

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