Photoorganocatalytic α-oxyamination of aldehydes

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Abstract

Methylene blue catalyzes the visible light-induced organocatalytic α-oxyamination of aldehydes via enamines. The irradiation of 3-phenylpropanal with TEMPO radical in the presence of morpholine as an organocatalyst and methylene blue as a photoredox catalyst gave the desired α-functionalized aldehyde in 75% yield.

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Ciszewski, L. W., Smolen, S., & Gryko, D. (2016). Photoorganocatalytic α-oxyamination of aldehydes. Arkivoc, 2017(2), 251–259. https://doi.org/10.3998/ark.5550190.p009.769

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