Abstract
Selective hydrogen production from formic acid with platinum nano-cluster dispersed by various protective polymer based agents polyvinylpyrrolidone (Pt-PVP) or polyacrylic acid (Pt-PAA) is attempted. The ratio of hydrogen to CO2 was estimated to be c.a. 1.0 (stoichiometric ratio) under the argon-saturated buffer solution containing formic acid with Pt-PVP.
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Minami, Y., Muroga, Y., Yoshida, T., & Amao, Y. (2019). Selective hydrogen production from formate using nanoparticle with homogeneously polymer-dispersed platinum clusters. Chemistry Letters, 48(8), 775–778. https://doi.org/10.1246/cl.190311
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