Abstract
The enantioselective kinetic resolution of two 3-phenyl-2-ketones using four different Baeyer-Villiger monooxygenases (BVMO) expressed recombinantly in Escherichia coli was studied. The highest enantioselectivity (E = 82) was achieved for 3-phenyl-2-butanone using a BVMO originating from Pseudomonas fluorescens. A BVMO from Pseudomonas putida showed an opposite (R)-enantiopreference and E = 12. © 2007 Elsevier Ltd. All rights reserved.
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CITATION STYLE
Geitner, K., Kirschner, A., Rehdorf, J., Schmidt, M., Mihovilovic, M. D., & Bornscheuer, U. T. (2007). Enantioselective kinetic resolution of 3-phenyl-2-ketones using Baeyer-Villiger monooxygenases. Tetrahedron Asymmetry, 18(7), 892–895. https://doi.org/10.1016/j.tetasy.2007.03.025
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