Journal Article

General preparation of functionalized o-nitroarylmagnesium halides through an iodine-magnesium exchange

Angewandte Chemie - International Edition (2002) 41(9) 1610-1611
DOI: 10.1002/1521-3773(20020503)41:9<1610::AID-ANIE1610>3.0.CO;2-T
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Abstract

Highly functionalized aryl Grignard reagents with an ortho-nitro substituent have been synthesized from 2-iodonitroaryl compounds through an I-Mg exchange reaction with PhMgCl or mesityl magnesium bromide (see scheme). These reagents are stable (T

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Sapountzis, I., & Knochel, P. (2002). General preparation of functionalized o-nitroarylmagnesium halides through an iodine-magnesium exchange. Angewandte Chemie - International Edition, 41(9), 1610–1611. https://doi.org/10.1002/1521-3773(20020503)41:9<1610::AID-ANIE1610>3.0.CO;2-T

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