First cage-like pentanuclear Co(II)-silsesquioxane

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Abstract

A new pentanuclear "cylinder"-like cobalt(ii) phenylsilsesquioxane [(PhSiO1.5)10(CoO)5(NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.

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Bilyachenko, A. N., Yalymov, A. I., Levitsky, M. M., Korlyukov, A. A., Es’Kova, M. A., Long, J., … Shul’Pin, G. B. (2016). First cage-like pentanuclear Co(II)-silsesquioxane. Dalton Transactions, 45(35), 13663–13666. https://doi.org/10.1039/c6dt02026g

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