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A [Mn18] wheel-of-wheels

Chemical Communications (2021) 57(34) 4122-4125
DOI: 10.1039/d1cc00185j
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Abstract

A [Mn18] wheel of wheels is obtained from the reaction of MnBr2·4H2O and LH3in MeOH. The metallic skeleton reveals two asymmetric [MnIII6MnII2] square wheels connected into a larger wheelviatwo MnIIions. Magnetic susceptibility and magnetisation data reveal competing exchange interactions, supported by computational studies.

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Coletta, M., Tziotzi, T. G., Gray, M., Nichol, G. S., Singh, M. K., Milios, C. J., & Brechin, E. K. (2021). A [Mn18] wheel-of-wheels. Chemical Communications, 57(34), 4122–4125. https://doi.org/10.1039/d1cc00185j

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