Palladium-catalyzed carbonylation/acyl migratory insertion sequence

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Abstract

Chemical Equation Presented On the move: A palladium-catalyzed reaction of aryl iodides, diazo compounds or N-tosylhyd razones, and carbon monoxide affords β-oxo esters or ketones/ enones (see scheme; DCE = l,2-dichloroethane). The products are delivered with high efficiency through the title sequence. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

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Zhang, Z., Liu, Y., Gong, M., Zhao, X., Zhang, Y., & Wang, J. (2010). Palladium-catalyzed carbonylation/acyl migratory insertion sequence. Angewandte Chemie - International Edition, 49(6), 1139–1142. https://doi.org/10.1002/anie.200906349

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