Reverse micelles in carbon dioxide with ionic-liquid domains

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Abstract

The fluorinated surfactant N-ethyl perfluorooctylsulfonamide can form reverse micelles with an ionic liquid as the inner component in supercritical CO2. These reverse micelles can solubilize salts and gold nanoparticles can be formed with HAuCl4 (see TEM image). The micellar systems may combine some of the advantages of supercritical CO2 and ionic liquids as solvents with benefits for potential applications. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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Liu, J., Cheng, S., Zhang, J., Feng, X., Fu, X., & Han, B. (2007). Reverse micelles in carbon dioxide with ionic-liquid domains. Angewandte Chemie - International Edition, 46(18), 3313–3315. https://doi.org/10.1002/anie.200605019

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