Abstract
The structure of the title salt, (C5H7N2)[Fe(C6H4O2)(C6H5O2)], consists of 3-Aminopyridinium cations and 1′-carboxyferrocene-1-carboxylate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe-C distances in the range 2.0270 (15)-2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle (Csubst-Cpcent-Cpcent-Csubst) equal to 66.0°. The conformations of other 1′-carboxyferrocene-1-carboxylate monoanions are compared and analyzed on the basis of literature data.
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Medved’ko, A. V., Churakov, A. V., Yu, H., Li, W., & Vatsadze, S. Z. (2017). Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate. Acta Crystallographica Section E: Crystallographic Communications, 73, 856–858. https://doi.org/10.1107/S2056989017007058
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