Experimental Study on Transport of Cd(II) and Cu(II) in Landfill Improved Clay Liners Building Material Containing Municipal Sludge-Activated Carbon

Abstract

Landfills necessitate a liner barrier system to prevent the leakage of contaminants into the surrounding soil. However, the currently employed compacted clay liner (CCL) is insufficient to prevent the leakage of heavy metal ions. This study proposes a novel landfill liner system utilizing sludge-based activated carbon (SAC)-modified clay. The adsorption characteristics of SAC-modified clay liner (SAC-CCL) for Cd(II) or Cu(II) were evaluated through batch tests. The permeability coefficient and unconfined compressive strength of SAC-CCL were assessed through permeation and unconfined compression tests. The permeability coefficient of the SAC-modified clay ranged from 2.57 × 10−9 to 1.10 × 10−8 cm/s. The unconfined compressive strength of the SAC-CCL varied between 288 and 531 kPa. The migration of Cd(II) or Cu(II) within an 80 cm thick, full-scale SAC-CCL was simulated using soil column tests. The diffusion coefficient (D) was calculated by inversion using the one-dimensional solute migration equation. The diffusion coefficients (D) for Cd(II) and Cu(II) ranged from 1.9 × 10−10 to 13.5 × 10−10 m2/s. The retardant performance of SAC-CCL for Cd(II) and Cu(II) followed the order: 3% SAC-CCL > 1% SAC-CCL > CCL > 5% SAC-CCL, from strongest to weakest. Consequently, SAC-modified clay demonstrates significant potential as a landfill lining material. However, the migration behavior of heavy metal ions in SAC-CCLs under cyclic dry–wet conditions requires further investigation.