A study on the principle of maximum dissipation for coupled and non-coupled non-isothermal processes in materials

Abstract

Onsager's principle of maximum dissipation (PMD) has proven to be an efficient tool to derive evolution equations for the internal variables describing non-equilibrium processes. However, a rigorous treatment of PMD for several simultaneously acting dissipative processes is still open and presented in this paper. The coupling or uncoupling of the processes is demonstrated via the mathematical structure of the dissipation function. Examples are worked out for plastic deformation and heat flux.