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Effective synthesis of optically active trifluoromethyldiazirinyl homophenylalanine and aroylalanine derivatives with the Friedel-Crafts reaction in triflic acid

Bioscience, Biotechnology and Biochemistry (2009) 73(6) 1377-1380
DOI: 10.1271/bbb.90027
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Abstract

The Friedel-Crafts reaction with 3-(3-methoxyphenyl)-3-(trifluoromethyl)- 3H-diazirine and optically active N-TFA-Asp(Cl)-OMe in triflic acid afforded homophenylalanine derivatives without any loss of the optical purity.

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Murashige, R., Murai, Y., Hatanaka, Y., & Hashimoto, M. (2009). Effective synthesis of optically active trifluoromethyldiazirinyl homophenylalanine and aroylalanine derivatives with the Friedel-Crafts reaction in triflic acid. Bioscience, Biotechnology and Biochemistry, 73(6), 1377–1380. https://doi.org/10.1271/bbb.90027

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