Abstract
Recent chemistry of four-membered ring selenium compounds is reviewed followed by a summary of work in our laboratories in this area. 2-Thia-6-selenaspiro[3.3]heptane has been synthesized for the first time. X-ray structures for the latter compound as well as for 2,6-dithiaspiro[3.3]heptane and 2,6-diselenaspiro[3.3]heptane have been determined. These compounds are useful as "rigid-rod" ligands for coordination to transition-metal complexes. © 2005 IUPAC.
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Block, E., Dikarev, E. V., Jin, J., Li, B., Petrukhina, M. A., & Zhang, S. Z. (2005). Synthesis, structure, and chemistry of selenium-containing four-membered rings. In Pure and Applied Chemistry (Vol. 77, pp. 2029–2032). https://doi.org/10.1351/pac200577122029
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