La Queglia carbonatitic melnöite: a notable example of an ultra-alkaline rock variant in Italy

Abstract

Very primitive ultramafic igneous rocks occur at Mt. La Queglia (Abruzzo, Italy). They form a strongly deformed sill–dyke system now tilted vertically. These rocks were initially classified as alnöite and, subsequently, have been suggested to be a carbonatitic olivine melilitite. However, further investigation and interpretation of these rocks is needed due to the presence of hand-specimen-scale textural variation suggesting a complex petrogenesis. We study the texture, mineral chemistry, and whole-rock geochemistry to define three main rock-types. (1) A brecciated rock with an ocellar texture composed of calcite pseudomorphs after olivine and melilite, plus fresh diopside in a groundmass of mica, aegirine, garnet, calcite, apatite, perovskite, titanate and chlorite. Zoned ocelli in this rock show an amoeboid shape, agglutination, and menisci typical of a plastic state. (2) A quenched rock showing a spinifex texture containing long feathery phenocrysts of cpx and mica suspended in a groundmass of nepheline, aegirine, apatite, Ti–rich magnetite, plus abundant calcite and some K-feldspar and zeolites. (3) A coarse-grained rock is composed of calcite plus intergranular glauconite, a mixture of spinel mineral group and Ti–rich magnetite, accessory barite, pyrite, and chabazite-K. The igneous rocks at Mt. La Queglia show extreme SiO2-undersaturation (33.5–37.3 wt% SiO2), high MgO contents and TiO2/Al2O3 ratios. Rock-type 1 has a lower Mg number Mg# = 100 × [Mg/(Mg + Fe2+)], higher Ca number Ca# = 100 × [Ca/(Ca + Mg)], high Cr (up to 720 ppm) Ni (up to 379 ppm), higher rare earth elements (REE) contents as well as La/Lu ratio, compared to rock-type 2. Perovskite and chromite accumulation seems an important agent during rock differentiation. Rock-type 3 shows REE cross-over with rock-type 2 suggesting light (L)REE concentration in a carbothermal residuum. Mt. La Queglia rocks are an end-member compared to other Upper Cretaceous and Paleogene Italian lamprophyres, suggesting a low degree of melting of a HIMU (a colloquialism for “high-μ”; referring to mantle domains with high 238U/ 204Pb) garnet-bearing mantle source.