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Phosphonate-substituted zirconium oxo clusters

Monatshefte fur Chemie (2015) 146(9) 1371-1374
DOI: 10.1007/s00706-015-1519-3
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Abstract

Abstract The phosphonate-substituted zirconium oxo clusters Zr6O2(OBu)12(O3PPh)4 and Zr7O2(OiPr)12(O3PCH2CH2CH2Br)6, with octahedrally coordinated Zr atoms, were synthesized by reaction of zirconium alkoxides with phosphonic acid bis(trimethylsilyl) esters. The basic structural motif are Zr3O(μ2-OR)3(OR)3 units which are connected in different ways.

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Czakler, M., & Schubert, U. (2015). Phosphonate-substituted zirconium oxo clusters. Monatshefte Fur Chemie, 146(9), 1371–1374. https://doi.org/10.1007/s00706-015-1519-3

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