Journal Article

Gold meets rhodium: Tandem one-pot synthesis of β-disubstituted ketones via meyer-schuster rearrangement and asymmetric 1,4-addition

Organic Letters (2013) 15(13) 3226-3229
DOI: 10.1021/ol4011739
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Abstract

An asymmetric one-pot tandem Au/Rh-catalyzed synthesis of highly enantioenriched β-disubstituted ketones starting from racemic propargyl alcohols is disclosed. The compatibility of the two metal complexes (Au/Rh) and their orthogonal ligand systems (NHC/diene) in this bimetallic catalytic system is investigated. © 2013 American Chemical Society.

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APA

Hansmann, M. M., Hashmi, A. S. K., & Lautens, M. (2013). Gold meets rhodium: Tandem one-pot synthesis of β-disubstituted ketones via meyer-schuster rearrangement and asymmetric 1,4-addition. Organic Letters, 15(13), 3226–3229. https://doi.org/10.1021/ol4011739

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