Geometric requirements and examples of important structures in the assembly of square building blocks

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Abstract

The basic structures for linking squares into polyhedra and networks (reticulation) are enumerated, and corresponding examples are described in which crystals were synthesized by linking paddle wheel (square) units into metal-organic frameworks (MOFs) - named MOF-102 to MOF-112.

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Eddaoudi, M., Kim, J., Vodak, D., Sudik, A., Wachter, J., O’Keeffe, M., & Yaghi, O. M. (2002). Geometric requirements and examples of important structures in the assembly of square building blocks. Proceedings of the National Academy of Sciences of the United States of America, 99(8), 4900–4904. https://doi.org/10.1073/pnas.082051899

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