Palladium(0)-catalyzed cross-couplings of 2-bromophosphinine

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Abstract

A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Kostenko, N., Ericsson, C., Engqvist, M., Gonzalez, S. V., & Bayer, A. (2013). Palladium(0)-catalyzed cross-couplings of 2-bromophosphinine. European Journal of Organic Chemistry, (22), 4756–4759. https://doi.org/10.1002/ejoc.201300710

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